Relocating and Jumping Ship

I'm currently in a back office function for a large foreign bank in New York and my position is being eliminated and moved to Charlotte. I'm willing to relocate as I went to college down there so my manager called me today and told me the position is officially posted and to apply. 

My goal is to move to a FO commercial or corporate banking position would it be frowned upon to start networking as soon as I relocate and if I get lucky leave within six months? 

Also I have a non-traditional degree (wealth management) and have been in the BO for 3 years now am I screwed? I am willing to start over as an An1.

Thanks in advance.